BADOCCO DENIS

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Structure Department of Chemical Sciences
Telephone 0498275179
Qualification Professore associato confermato
Scientific sector CHIM/01 - ANALYTICAL CHEMISTRY
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Office hours
VII piano interchimico via marzolo 1 è possibile concordare l'orario e il giorno del ricevimento. Scrivere una mail
(updated on 02/05/2017 08:55)

Proposals for thesis
Argomenti di tesi
1. Sviluppo di nuovi sensori ottici per la determinazione dell'O2 in matrici complesse. Es. per seguire il processo di invecchiamento del vino...........)
2. Sviluppo di nuovi sensori di pH basati sull'elaborazione di immagini.
3. Sviluppo di nuovi algoritmi basati sulla statistica non parametrica per l'analisi multivariata dei dati chimici. Supporto: MATLAB
4. Validazione di Metodi analitici per l'analisi di campioni organici/inorganici (ICP-MS e ICP-OES)
5. Elettrochemiluminescenza (ECL) e simulazione.
6. Elettroanalitica (studio di farmaci leganti)
7. Studio di complessi metallo-legante e delle cinetiche di formazione pH-statica e HPLC-ICP-MS)

Curriculum Vitae
Curriculum vitae & studiorum.
Born at Pordenone on 1971. 1989: undergraduate in chemistry (60/60). 2001: Degree in Chemistry cum laude. 2002: Get a grant from Titolchimica and works on the optimization of reactants for COD and Karl-Fisher determination. 2003: He specializes in chemiometry, and Mass spectrometry. 2006: get the degree of PhD. In Chemical Sciences. Winner of a competitive examination becomes Researcher (CHIM01) at the Department of Chemical Sciences of the University of Padova. 2008-2011: received a grant from the University of Padova (PRAT2008) titled: “Building and characterization of oxygen sensor based on luminescence quenching of molecules embedded in organic, inorganic or hybrid polymeric thin films and applications in environmental and ambiental field” 2009-2011 collaborates with CLR s.r.l. (Rodano) and with AMEL s.r.l. (Milan) for the production of innovative optical fiber based optical sensors and polymers in order to obtain prototypes for oxygen detection in harsh environments, such as in high temperatures and high humidity ones. Dr. Denis Badocco is co-author of 53 publications in international journals, all related to analytical chemistry, and attended several national symposia. She has collected about 598 citations reaching an H-index (Hirsch index) value of 12.

Research areas
1 - Fine research
a) Electrochemiluminescent (ECL) processes mainly based on Ruthenium complexes: study of the mechanisms of the involved reactions with tertiary aliphatic amines (also with the use of digital simulation techniques), analytical applications and construction of ECL sensors.
b) Construction of gas sensors based on the fluorescence of Ruthenium complexes included in polymeric layers.
c) Statistical studies as part of the validation of analytical methods.
2 - Analytical Chemistry applied to the quantification of species of industrial, food and environmental interest. Examples: determination of biogenic amines in chocolate with IC coupled to pulsed amperometry; determination of cyanide and sulphide in waste and surface water with IC coupled to pulsed amperometry at Ag electrode; determination of VOX in soils with HS-SPME coupled to GC-ECD.

Publications
1 D. BADOCCO, MONDIN A, FUSAR A, FAVARO G, PASTORE P (2009)
Influence of the Real Background Signal on the Linearity of the Stern-Volmer Calibration for the Determination of Molecular Oxygen with Optical Sensors.
JOURNAL OF PHYSICAL CHEMISTRY. C, NANOMATERIALS AND INTERFACES, vol. 113, p. 15742-15750, ISSN: 1932-7447, doi: 10.1021/jp9050676

2 D. BADOCCO, MONDIN A., FUSAR A, PASTORE P (2009)
Calibration models under dynamic conditions for determining molecular oxygen with optical sensors based on luminescence quenching of transition metal complexes embedded in polymeric matrices.
JOURNAL OF PHYSICAL CHEMISTRY. C, NANOMATERIALS AND INTERFACES, vol. 113, p. 20467-20475, ISSN: 1932-7447, doi: 10.1021/jp906059m

3 D. BADOCCO, ANDREA MONDIN, P. PASTORE (2011)
Rationalization of the behaviour of a bi-label oxygen optical sensor.
SENSORS AND ACTUATORS. B, CHEMICAL, vol. 158, p. 54-61, ISSN: 0925-4005, doi: 10.1016/j.snb.2011.05.024

4 D. BADOCCO, A. MONDIN, P. PASTORE (2012)
Determination of thermodynamic parameters from light intensity signals obtained from oxygen optical sensors.
SENSORS AND ACTUATORS. B, CHEMICAL, vol. 163, p. 165-170, ISSN: 0925-4005, doi: 10.1016/j.snb.2012.01.030

5 D. BADOCCO, ANDREA MONDIN, PAOLO PASTORE (2013)
Signal drift of oxygen optical sensors. Part I: Rationalization of the drift nature and its experimental check with a light intensity detection based sensor.
SENSORS AND ACTUATORS. B, CHEMICAL, vol. 181, p. 943-948, ISSN: 0925-4005, doi: 10.1016/j.snb.2012.12.040

6 D. BADOCCO, ANDREA MONDIN, PAOLO PASTORE (2013)
Signal drift of oxygen optical sensors. Part II: “Smart” drift correction algorithm and its experimental check with a light intensity detection based sensor.
SENSORS AND ACTUATORS. B, CHEMICAL, vol. 181, p. 949-954, ISSN: 0925-4005, doi: 10.1016/j.snb.2012.12.045

List of taught course units in A.Y. 2019/20
Degree course code (?) Degree course track Course unit code Course unit name Credits Year Period Lang. Teacher in charge
SC1156 COMMON SC09101131 10 3rd Year (2019/20) First
semester
ITA PAOLO PASTORE
SC1157 COMMON SC09101131 10 3rd Year (2019/20) First
semester
ITA PAOLO PASTORE
SC1163 COMMON SCP3049590 9 3rd Year (2019/20) First
semester
ITA STEFANO AGNOLI
SC1169 COMMON SC01122926 6 1st Year (2019/20) Second
semester
ITA DENIS BADOCCO