First cycle
degree courses
Second cycle
degree courses
Single cycle
degree courses
School of Science
CHEMISTRY
Course unit
PHYSICAL CHEMISTRY 1
SC06101274, A.A. 2019/20

Information concerning the students who enrolled in A.Y. 2018/19

Information on the course unit
Degree course First cycle degree in
CHEMISTRY
SC1156, Degree course structure A.Y. 2014/15, A.Y. 2019/20
N0
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Number of ECTS credits allocated 10.0
Type of assessment Mark
Course unit English denomination PHYSICAL CHEMISTRY 1
Department of reference Department of Chemical Sciences
Mandatory attendance No
Language of instruction Italian
Branch PADOVA
Single Course unit The Course unit can be attended under the option Single Course unit attendance
Optional Course unit The Course unit can be chosen as Optional Course unit

Lecturers
Teacher in charge ANTONINO POLIMENO CHIM/02
Other lecturers MIRCO ZERBETTO CHIM/02

ECTS: details
Type Scientific-Disciplinary Sector Credits allocated
Core courses CHIM/02 Physical Chemistry 10.0

Course unit organization
Period First semester
Year 2nd Year
Teaching method frontal

Type of hours Credits Teaching
hours
Hours of
Individual study
Shifts
Practice 3.0 30 45.0 No turn
Lecture 7.0 56 119.0 No turn

Calendar
Start of activities 30/09/2019
End of activities 18/01/2020
Show course schedule 2019/20 Reg.2014 course timetable

Syllabus
Prerequisites: Basic notions of analysis (differential calculus): real functions, derivatives, integrals
Target skills and knowledge: Principles, methods and applications of thermodynamics of systems at equilibrium; principles of chemical kinetics
Examination methods: The verification of the knowledge and expected skills will be carried out on the basis of two separate tests. The first test, written, will be based on two assessments (partial tests) in the form of numerical exercises applied to properties of thermochemical systems; the second testwill be based on an oral discussion.

The first partial test will take place approximately around the middle of the semester, the second at its conclusion. Each partial test will be based on four or five numerical exercises.

The final oral exam will be based on open questions on the main themes developed during the course.

The final grade will be obtained from the average of the marks reported in the partial tests and in the oral test.
Assessment criteria: Assessment will be based on comprehension skills and capability of applying thereotical principles to actual physico-chemical problems.
Course unit contents: Thermodynamics
- The gas laws
- The van der Waals equation
- The principle of corresponding states
- Work, heat, and energy
- The internal energy
- Expansion work
- Heat transactions and enthalpy
- Standard enthalpy changes and enthalpies of formation
- The temperature-dependence of reaction enthalpies
- State functions
- Exact and inexact differentials
- Changes in internal energy
- The Joule–Thomson effect
- The dispersal of energy
- Entropy, entropy changes accompanying specific processes
- The Third Law of thermodynamics
- The Helmholtz and Gibbs energies
- Standard reaction Gibbs energies
- Supercritical fluids
- Partial molar quantities
- The thermodynamics of mixing
- The chemical potentials of liquids
- Colligative properties
- The activities of regular solutions
- The activities of ions in solution
- Phases, components, and degrees of freedom
- The phase rule
- Two-component systems
- Vapour pressure diagrams
- Temperature–composition diagrams
- The Gibbs energy minimum
- The description of equilibrium
- The response of equilibria to pressure
- The response of equilibria to temperature
- Half-reactions and electrodes
- Varieties of cells
- The electromotive force
- Standard potentials
- Applications of standard potentials
- Empirical chemical kinetics
- Experimental techniques
- The rates of reactions
- Enzymes kinetics
Planned learning activities and teaching methods: Frontal lectures and numerical exercises
Additional notes about suggested reading: Lecture notes for advanced topics
Textbooks (and optional supplementary readings)
  • P. Atkins, J. De Paula, Physical Chemistry. --: Oxford University Press, --. Cerca nel catalogo