First cycle
degree courses
Second cycle
degree courses
Single cycle
degree courses
School of Science
CHEMISTRY
Course unit
MAGNETOCHEMISTRY
SCN1036202, A.A. 2018/19

Information concerning the students who enrolled in A.Y. 2017/18

Information on the course unit
Degree course Second cycle degree in
CHIMICA (Ord. 2015)
SC1169, Degree course structure A.Y. 2015/16, A.Y. 2018/19
N0
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Number of ECTS credits allocated 6.0
Type of assessment Mark
Course unit English denomination MAGNETOCHEMISTRY
Website of the academic structure http://www.chimica.unipd.it/corsi/corsi-di-laurea-magistrale/laurea-magistrale-chimica
Department of reference Department of Chemical Sciences
E-Learning website https://elearning.unipd.it/chimica/course/view.php?idnumber=2018-SC1169-000ZZ-2017-SCN1036202-N0
Mandatory attendance No
Language of instruction Italian
Branch PADOVA
Single Course unit The Course unit can be attended under the option Single Course unit attendance
Optional Course unit The Course unit can be chosen as Optional Course unit

Lecturers
Teacher in charge MARCO RUZZI CHIM/02
Other lecturers ANTONIO TOFFOLETTI CHIM/02

ECTS: details
Type Scientific-Disciplinary Sector Credits allocated
Core courses CHIM/02 Physical Chemistry 6.0

Course unit organization
Period First semester
Year 2nd Year
Teaching method frontal

Type of hours Credits Teaching
hours
Hours of
Individual study
Shifts
Lecture 6.0 48 102.0 No turn

Calendar
Start of activities 01/10/2018
End of activities 18/01/2019
Show course schedule 2019/20 Reg.2018 course timetable

Examination board
Board From To Members of the board
3 a.a. 2018/19 27/01/2014 30/11/2019 RUZZI MARCO (Presidente)
BARBON ANTONIO (Membro Effettivo)
TOFFOLETTI ANTONIO (Membro Effettivo)

Syllabus
Target skills and knowledge: The aim of the course is understanding cooperation properties in magnetic materials from the magnetic features of atoms, radicals and magnetic clusters (Magnetochemistry) and the effects of these magnetic properties on the photoinduced chemical reactions (Spin-Chemistry). Corresponding experimental methods will be introduced, as well as the potential applications in the field of data storage and photovoltaics processes.
Examination methods: Oral examination of about 40 minutes involves two open general questions with the aim of assessing the knowledge of two main topics treated in the course. A number of different specific questions will allow to evaluate the reasoning ability of the candidate about more detailed issues.
Course unit contents: Introduction to phenomenology and principles of magnetism. Paramagnetism and diamagnetism. Long-range order and cooperation: ferromagnetism, antiferromagnetism, ferrimagnetism.
The elementary concepts of paramagnetism and diamagnetism. Brillouin’s equation and Curie-Weiss law. Some Curie law magnets. The Van Vleck’s theory for paramagnetism and diamagnetism. Magnetic properties of metals: paramagnetism of Pauli and diamagnetism of Landau.
Measurement of magnetic susceptibility: the Gouy methods. NMR tecniques. Dipole moments methods: SQUID magnetometry.
Electronic structure of atoms and implications for magnetism. Angular momenta and magnetic moments. Coupling of angular momenta. The electron spin-orbit interactions: perturbation theory and the mixing of states. Spin Hamiltonian and wavefunctions in the Hilbert space. Spin-Spin dipolar interactions and Zero Field Splitting theory. Spin exchange interactions. Superexchange. Ising and Heisenberg models. Ferromagnets and ferrimagnets.
Magnetic properties of free ions. Transition metal ions. The orbital splitting in cubic ligand fields and lower than cubic symmetry systems. Origin of ferromagnetism in inorganic materials. Magnetic properties of molecular crystals. Nanomagnets: magnetism in single molecule systems (SMM) and clusters of ions. Some applications of nanomagnets.
Radicals and biradicals. Photoexcited transient paramagnetic species in photoactive organic materials. Spin polarization processes. Spin-correlated radical ions pairs theory. Polarons and bipolarons in polymeric systems. Spin selective mechanisms in photovoltaics processes. Some applications in spintronics.
Planned learning activities and teaching methods: Classroom lectures.
Additional notes about suggested reading: In-class slides and post-class material will be provided on the whole program of the course.
Textbooks (and optional supplementary readings)
  • Orchard, A.F., Magnetochemistry. Oxford: Oxford University Press, 2003. Cerca nel catalogo
  • Carlin, Richard L., Magnetochemistry. Berlin: Springer-Verlag, 1986. Cerca nel catalogo